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★ The first non-acid catalytic synthesis of tert-butyl ether from tert-butyl alcohol using ionic liquid as dehydrator

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The first non-acid catalytic synthesis of tert-butyl ether from tert-butyl alcohol using ionic liquid as dehydrator
石峰 / 邓友全
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Methyl tert-butyl ether (MTBE), ethyl tert-butyl ether (ETBE), and isopropyl tert-butyl ether (IPTBE) have been synthesized for the first time over a non-acid ionic liquid as catalyst and dehydrator with high conversion ( > 90%) and selectivity ( > 90%) under mild conditions.

★★★★☆ Feng Shi, Hai Xiong, Yanlong Gu, Shu Guo and Youquan Deng. CHEM. COMMUN. , 2003, 1054–1055.