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★ Investigation of the intrinsic electric field of nonhydroxyl and hydroxyl ionic liquids by vibrational Stark effect spectroscopy
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Investigation of the intrinsic electric field of nonhydroxyl and hydroxyl ionic liquids by vibrational Stark effect spectroscopy |
张世国 / 邓友全 |
604.61 KB |
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Electric fields of ionic liquids (ILs) were investigated by vibrational Stark effect spectroscopy using ethyl thiocyanate as a probe molecule. It was found that the stretching vibration of C≡N in nonhydroxyl ILs originates exclusively from the intrinsic electric fields, which are on average 3.0 MV cm-1 higher than those of molecular solvents. In contrast, in the case of hydroxyl functional ILs, hydrogen bonding as well as the electric field contribute to the IR shift of C≡N. ★★★☆☆ Zhang SG,Zhang Y,Deng YQ. Investigation Of The Intrinsic Electric Field Of Nonhydroxyl And Hydroxyl Ionic Liquids By Vibrational Stark Effect Spectroscopy[J]. Rsc Advances,2013,3:11480-11484. |