1-甲基咪唑硫酸氢盐
N-methylimidazolium hydrogen sulfate
- 分子式：C4H8N2O4S
- 分子量：180.18
- CAS编号：681281-87-8
- 纯度：98%
基本信息
| 产品名称： | 1-甲基咪唑硫酸氢盐 | ||
| 英文名称： | N-methylimidazolium hydrogen sulfate | ||
| CAS编号： | 681281-87-8 | 简 写： | MImHSO4 |
| 分 子 式 ： | C4H8N2O4S | 分 子 量 ： | 180.18 |
| 纯 度： | 98% | 产品编号： | CP0433 |
物性数据
| 项目 | 数据 | 测试条件 | 测试方法 | 数据来源 |
| 表面张力 mN/m | 53.9 | 20℃,101KPa | 液体, Ring tensiometer | ILThermo |
| 玻璃化温度 ℃ | -99 | SciFinder | ||
| 电导率 mS/cm | 6.5 | 30℃ | SciFinder | |
| 密度 g/mL | 1.4622 | 20℃,101KPa | 液体, Vibrating tube method | ILThermo |
| 热分解温度 ℃ | 320 | SciFinder | ||
| 熔点 ℃ | 21 | DSC/DTA | ILThermo | |
| 粘度 cP | 563 | 20℃,101KPa | 液体, Concentric cylinders viscometry | ILThermo |
| 折光率 | 1.4887 | 25℃,101KPa | 液体, Standard Abbe refractometry | ILThermo |
参考谱图
1-甲基咪唑硫酸氢盐,N-methylimidazolium hydrogen sulfate,MImHSO4,681281-87-8,NMR,H谱,氘代DMSO
Mehdi, Hasan; Journal of Organic Chemistry, (2007), 72(2), 517-524, CAplus
1-甲基咪唑硫酸氢盐,N-methylimidazolium hydrogen sulfate,MImHSO4,681281-87-8,NMR,C谱,氘代DMSO
Mehdi, Hasan; Journal of Organic Chemistry, (2007), 72(2), 517-524, CAplus
1-甲基咪唑硫酸氢盐,N-methylimidazolium hydrogen sulfate,MImHSO4,681281-87-8,NMR,H谱,D2O
Han, Feng; Organic & Biomolecular Chemistry, (2012), 10(2), 346-354, CAplus
1-甲基咪唑硫酸氢盐,N-methylimidazolium hydrogen sulfate,MImHSO4,681281-87-8,NMR,C谱,D2O
Han, Feng; Organic & Biomolecular Chemistry, (2012), 10(2), 346-354, CAplus
安全信息
| Code |
Hazard Statement |
Source |
| H341 |
Suspected of causing genetic defects |
European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria |
| H335 |
May cause respiratory irritation |
Expert Curated |
| H318 |
Causes serious eye damage |
Expert Curated |
Other Names and Identifiers
Canonical SMILES
O=S(=O)(O)O.N=1C=CN(C1)C
InChI
InChI=1S/C4H6N2.H2O4S/c1-6-3-2-5-4-6;1-5(2,3)4/h2-4H,1H3;(H2,1,2,3,4)
InChI Key
TVEOIQKGZSIMNG-UHFFFAOYSA-N
5 Other Names for this Substance
- 1-Methylimidazole hydrogen sulfate
- 1-Methylimidazolium hydrogen sulfate
- 1H-3-Methylimidazolium hydrogen sulfate
- Basionics AC 39
- N-Methylimidazolium hydrogen sulfate
参考文献
Experimental Properties
Density
Thermal
- (1) Ogihara, Wataru; Chemical Communications (Cambridge, United Kingdom), (2006)(34), 3637-3639, CAplus
- (2) Hajipour, Abdol R.; Catalysis Communications, (2007), 9(1), 89-96, CAplus
- (3) Tao, Duan-Jian; Chemical Engineering Journal (Amsterdam, Netherlands), (2011), 171(3), 1333-1339, CAplus
- (4) Tao, Duan-Jian; Industrial & Engineering Chemistry Research, (2011), 50(4), 1989-1996, CAplus
- (5) Chiappe, Cinzia; Green Chemistry, (2013), 15(1), 137-143, CAplus
- (6) Sun, Aijun; Chinese Journal of Chemistry, (2009), 27(9), 1741-1748, CAplus
- (7) Gutowski, Keith E.; Journal of Physical Chemistry B, (2005), 109(49), 23196-23208, CAplus
- (8) Ogihara, Wataru; Chemical Communications (Cambridge, United Kingdom), (2006)(34), 3637-3639, CAplus
- (9) Sun, Aijun; Chinese Journal of Chemistry, (2009), 27(9), 1741-1748, CAplus
- (10) Tao, Duan-Jian; Industrial & Engineering Chemistry Research, (2011), 50(4), 1989-1996, CAplus
- (11) Tao, Duan-Jian; Chemical Engineering Journal (Amsterdam, Netherlands), (2011), 171(3), 1333-1339, CAplus
- (12) Long, Jin-Xing; Bioresource Technology, (2011), 102(21), 10114-10123, CAplus
Experimental Spectra
1H-NMR
- (1) Ullah, Zahoor; RSC Advances, (2015), 5(87), 71449-71461, CAplus
- (2) Mehdi, Hasan; Journal of Organic Chemistry, (2007), 72(2), 517-524, CAplus
- (3) Li, Yu-Nong; Green Chemistry, (2012), 14(10), 2752-2758, CAplus
- (4) Patil, Sandip K.; Research on Chemical Intermediates, (2017), 43(10), 5365-5376, CAplus
- (5) Song, Dayong; Synthetic Communications, (2018), 48(6), 692-698, CAplus
- (6) Khan, Amir Sada; Journal of Chemical & Engineering Data, (2017), 62(10), 2993-3003, CAplus
- (7) Chiappe, Cinzia; Green Chemistry, (2013), 15(1), 137-143, CAplus
- (8) Carlesi Jara, Carlos; Chemical Engineering Journal (Amsterdam, Netherlands), (2011), 171(3), 1253-1262, CAplus
- (9) Manna, Arpan; Journal of Physical Chemistry B, (2014), 118(9), 2487-2498, CAplus
- (10) Mehdi, Hasan; Journal of Organic Chemistry, (2007), 72(2), 517-524, CAplus
- (11) Deshmukh, Krishna M.; Canadian Journal of Chemistry, (2009), 87(2), 401-405, CAplus
- (12) Sun, Aijun; Chinese Journal of Chemistry, (2009), 27(9), 1741-1748, CAplus
- (13) Tong, Xinli; ChemSusChem, (2010), 3(3), 350-355, CAplus
- (14) Tong, Xinli; Carbohydrate Research, (2010), 345(12), 1698-1701, CAplus
- (15) Deshmukh, Krishna M.; Catalysis Communications, (2010), 12(3), 207-211, CAplus
- (16) Tao, Duan-Jian; Industrial & Engineering Chemistry Research, (2011), 50(4), 1989-1996, CAplus
- (17) Liu, Xiumei; Green Chemistry, (2011), 13(3), 697-701, CAplus
- (18) Tao, Duan-Jian; Chemical Engineering Journal (Amsterdam, Netherlands), (2011), 171(3), 1333-1339, CAplus
13C-NMR
- (1) Mehdi, Hasan; Journal of Organic Chemistry, (2007), 72(2), 517-524, CAplus
- (2) Song, Dayong; Synthetic Communications, (2018), 48(6), 692-698, CAplus
- (3) Chiappe, Cinzia; Green Chemistry, (2013), 15(1), 137-143, CAplus
- (4) Carlesi Jara, Carlos; Chemical Engineering Journal (Amsterdam, Netherlands), (2011), 171(3), 1253-1262, CAplus
- (5) Mehdi, Hasan; Journal of Organic Chemistry, (2007), 72(2), 517-524, CAplus
- (6) Tong, Xinli; Carbohydrate Research, (2010), 345(12), 1698-1701, CAplus
