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1-乙基-3-甲基咪唑双（三氟甲烷磺酰）亚胺盐

1-Ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide

  • 分子式：C8H11F6N3O4S2
  • 分子量：391.31
  • CAS编号：174899-82-2
  • 纯度：99%

  • 基本信息

    产品名称： 1-乙基-3-甲基咪唑双（三氟甲烷磺酰）亚胺盐
    英文名称： 1-ethyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide
    CAS编号： 174899-82-2 简      写： EMImNTf2
    分 子 式 ： C8H11F6N3O4S2 分 子 量 ： 391.31
    纯      度： 99% 产品编号： CP0058

  • 物性数据

    项目 数据 测试条件 测试方法 数据来源
    long-term热稳定性  ℃ 222 2014客户文章
    饱和蒸汽压  Pa 0.006 170℃   2012客户文章
    表面张力  mN/m 35.7  25℃,101KPa  液体, Pendant drop shape  ILThermo
    纯度H2O  ppm 231   323-343K真空干燥24h 2012客户文章
    纯度H2O  ppm 37   60℃真空干燥96h，50℃、N2净化减重<0.005%/min 2012客户文章
    电导率  mS/cm 9.15  25℃,101KPa  液体, Alternating current cell with electrodes  ILThermo
    电化学窗口  V 4.3     2014年整理
    密度  g/mL 1.5382 5℃ H2O<70ppm,卤素<100ppm 2015论文
    密度  g/mL 1.5286 15℃ Br-<50ppm,H2O=276ppm 2018客户文章
    密度  g/mL 1.5235 20℃ Br-<50ppm,H2O=276ppm 2018客户文章
    密度  g/mL 1.519 25℃ 323-343K真空干燥24h 2012客户文章
    密度  g/mL 1.5189  25℃,101KPa  液体, Vibrating tube method  ILThermo
    密度  g/mL 1.5184 25℃ Br-<50ppm,H2O=276ppm 2018客户文章
    密度  g/mL 1.5178 25℃ H2O<70ppm,卤素<100ppm 2015论文
    密度  g/mL 1.5133 30℃ Br-<50ppm,H2O=276ppm 2018客户文章
    密度  g/mL 1.5083 35℃ Br-<50ppm,H2O=276ppm 2018客户文章
    密度  g/mL 1.5033 40℃ Br-<50ppm,H2O=276ppm 2018客户文章
    密度  g/mL 1.4983 45℃ Br-<50ppm,H2O=276ppm 2018客户文章
    密度  g/mL 1.4977 45℃ H2O<70ppm,卤素<100ppm 2015论文
    密度  g/mL 1.4933 50℃ Br-<50ppm,H2O=276ppm 2018客户文章
    密度  g/mL 1.4883 55℃ Br-<50ppm,H2O=276ppm 2018客户文章
    密度  g/mL 1.4779 65℃ H2O<70ppm,卤素<100ppm 2015论文
    热导率  W/(m.K) 0.1202 293.15K   2014客户文章
    热分解onset温度  ℃ 419     2014客户文章
    热分解peak温度  ℃ 457     2014客户文章
    热分解start温度  ℃ 320     2014客户文章
    热分解温度  ℃ 426.8     实验实测
    熔点  ℃ -18±2    DSC/DTA  ILThermo
    粘度  cP 75.08 5℃ H2O<70ppm,卤素<100ppm 2015论文
    粘度  cP 49.41 15℃ Br-<50ppm,H2O=276ppm 2018客户文章
    粘度  cP 40.36 20℃ Br-<50ppm,H2O=276ppm 2018客户文章
    粘度  cP 33.52 25℃ Br-<50ppm,H2O=276ppm 2018客户文章
    粘度  cP 33.5  25℃,101KPa  液体, Capillary tube (Ostwald; Ubbelohde) method  ILThermo
    粘度  cP 32.02 25℃ H2O<70ppm,卤素<100ppm 2015论文
    粘度  cP 28.35 30℃ Br-<50ppm,H2O=276ppm 2018客户文章
    粘度  cP 24.15 35℃ Br-<50ppm,H2O=276ppm 2018客户文章
    粘度  cP 20.76 40℃ Br-<50ppm,H2O=276ppm 2018客户文章
    粘度  cP 17.9 45℃ Br-<50ppm,H2O=276ppm 2018客户文章
    粘度  cP 17.32 45℃ H2O<70ppm,卤素<100ppm 2015论文
    粘度  cP 15.93 50℃ Br-<50ppm,H2O=276ppm 2018客户文章
    粘度  cP 14.26 55℃ Br-<50ppm,H2O=276ppm 2018客户文章
    粘度  cP 10.82 65℃ H2O<70ppm,卤素<100ppm 2015论文
    折光率   1.4231  25℃,101KPa  液体, Standard Abbe refractometry  ILThermo
    折光率   1.419     2012客户文章

  • 参考谱图

    1-乙基-3-甲基咪唑双（三氟甲烷磺酰）亚胺盐,1-ethyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide,EMImNTf2,174899-82-2, 核磁 NMR, H谱, 氘代DMSO
    1-乙基-3-甲基咪唑双（三氟甲烷磺酰）亚胺盐,1-ethyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide,EMImNTf2,174899-82-2,
    核磁 NMR, H谱, 氘代DMSO
    1-乙基-3-甲基咪唑双（三氟甲烷磺酰）亚胺盐,1-ethyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide,EMImNTf2,174899-82-2, 核磁 NMR, H谱, 氘代丙酮
    1-乙基-3-甲基咪唑双（三氟甲烷磺酰）亚胺盐,1-ethyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide,EMImNTf2,174899-82-2,
    核磁 NMR, H谱, 氘代丙酮
    1-乙基-3-甲基咪唑双（三氟甲烷磺酰）亚胺盐,1-ethyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide,EMImNTf2,174899-82-2, 核磁 NMR, C谱, 氘代丙酮
    1-乙基-3-甲基咪唑双（三氟甲烷磺酰）亚胺盐,1-ethyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide,EMImNTf2,174899-82-2,
    核磁 NMR, C谱, 氘代丙酮

  • 安全信息

    Code
    Hazard Statement
    Source
    H412
    Harmful to aquatic life with long lasting effects
    European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria
    H411
    Toxic to aquatic life with long lasting effects
    European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most common notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria
    H401
    Toxic to aquatic life
    TCI America
    H335
    May cause respiratory irritation
    Expert Curated
    H333
    May be harmful if inhaled
    Expert Curated
    H319
    Causes serious eye irritation
    European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, Strem Chemicals
    H315
    Causes skin irritation
    European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, Strem Chemicals
    H314
    Causes severe skin burns and eye damage
    European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most common notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, TCI America
    H313
    May be harmful in contact with skin
    Expert Curated
    H311
    Toxic in contact with skin
    European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most common notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria
    H303
    May be harmful if swallowed
    Expert Curated
    H302
    Harmful if swallowed
    TCI America
    H301
    Toxic if swallowed
    European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most common notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, TCI America

  • Other Names and Identifiers

    Canonical SMILES
    O=S(=O)([N-]S(=O)(=O)C(F)(F)F)C(F)(F)F.C1=C[N+](=CN1C)CC
    InChI
    InChI=1S/C6H11N2.C2F6NO4S2/c1-3-8-5-4-7(2)6-8;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8/h4-6H,3H2,1-2H3;/q+1;-1
    InChI Key
    LRESCJAINPKJTO-UHFFFAOYSA-N
    36 Other Names for this Substance
    • 1H-Imidazolium, 1-ethyl-3-methyl-, salt with 1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamide (1:1) (9CI)
    • Methanesulfonamide, 1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]-, ion(1-), 1-ethyl-3-methyl-1H-imidazolium (9CI)
    • 1-Ethyl-3-methyl-1-H-imidazolium bis(trifluoromethansulfonyl)imide
    • 1-Ethyl-3-methyl-1H-imidazolium bis(trifluoromethanesulfonyl)imide
    • 1-Ethyl-3-methyl-1H-imidazolium bis(trifluoromethylsulfonyl)imide
    • 1-Ethyl-3-methyl-1H-imidazolium salt with 1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamide
    • 1-Ethyl-3-methylimidazolinium bis(trifluoromethylsulfonyl)imide
    • 1-Ethyl-3-methylimidazolium bis(trifluoromethanesulfone)imide
    • 1-Ethyl-3-methylimidazolium bis(trifluoromethanesulfonimide)
    • 1-Ethyl-3-methylimidazolium bis(trifluoromethanesulfonimide) salt
    • 1-Ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide
    • 1-Ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide(1-)
    • 1-Ethyl-3-methylimidazolium bis(trifluoromethanesylfonyl)imide(1-)
    • 1-Ethyl-3-methylimidazolium bis(trifluoromethylsufonyl)imide
    • 1-Ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)amide
    • 1-Ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imidate(1-)
    • 1-Ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide
    • 1-Ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide(1-)
    • 1-Ethyl-3-methylimidazolium bis(trifluorosulfonyl)imide
    • 1-Ethyl-3-methylimidazolium bis(triflyl)amide
    • 1-Ethyl-3-methylimidazolium bis[(trifluoromethyl)sulfonyl]amide
    • 1-Ethyl-3-methylimidazolium bistriflimide
    • 1-Ethyl-3-methylimidazolium triflimide
    • 1-Ethyl-3-methylimidizolium bis(trifluoromethane sulfonyl)imide
    • 1-Methyl-3-ethylimidazolium bis(trifluoromethylsulfonyl)imide
    • 3-Ethyl-1-methylimidazolium bis(trifluoromethanesulfonyl)imide
    • [C2Mim+][Tf2N-]
    • [EMIM][TFSI]
    • A 79426
    • Basionics HP 01
    • Elexcel IL 210
    • EMI-TFSI
    • EMIm bis(trifluoromethanesulfonyl)amide
    • EMIN 111
    • Ethylmethylimidazolium bis(trifluoromethanesulfonyl)imide
    • IL 210

  • 参考文献

    Experimental Properties

    Acoustic

    Chemical

    Density

    Electrical

    Flow and Diffusion

    Interface

    Lipinski

    Mechanical

    Optical and Scattering

    Structure Related

    Thermal

    Experimental Spectra

    1H-NMR

    13C-NMR

    Additional Spectra

    hetero NMR

    IR

    Mass

    Raman

    UV and Visible

    X-Ray