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1-丁基-3-甲基咪唑六氟磷酸盐

1-butyl-3-methylimidazolium hexafluorophosphate

  • 分子式：C8H15F6N2P
  • 分子量：284.18
  • CAS编号：174501-64-5
  • 纯度：99%

  • 基本信息

    产品名称： 1-丁基-3-甲基咪唑六氟磷酸盐
    英文名称： 1-butyl-3-methylimidazolium hexafluorophosphate
    CAS编号： 174501-64-5 简      写： BMImPF6
    分 子 式 ： C8H15F6N2P 分 子 量 ： 284.18
    纯      度： 99% 产品编号： CP0083

  • 物性数据

    项目 数据 测试条件 测试方法 数据来源
    long-term热稳定性  ℃ 248 2014客户文章
    表面张力  mN/m 49.57 20℃   2011客户文章
    表面张力  mN/m 48.51 25℃   2011客户文章
    表面张力  mN/m 47.03 32℃   2011客户文章
    表面张力  mN/m 44.9 42℃   2011客户文章
    表面张力  mN/m 43  25℃,101KPa  液体, Ring tensiometer  ILThermo
    表面张力  mN/m 42.57 53℃   2011客户文章
    表面张力  mN/m 40.44 63℃   2011客户文章
    纯度H2O  ppm <100   室温真空干燥数天 2012客户文章
    纯度H2O  ppm 663   323-343K真空干燥24h 2012客户文章
    电导率  mS/cm 1.465  25℃,101KPa  液体, Alternating current cell with electrodes  ILThermo
    电化学窗口  V 4.6      
    密度  g/mL 1.3717 20℃   2011客户文章
    密度  g/mL 1.37 25℃ 323-343K真空干燥24h 2012客户文章
    密度  g/mL 1.3676  25℃,101KPa  液体, Vibrating tube method  ILThermo
    密度  g/mL 1.3674 25℃   2011客户文章
    密度  g/mL 1.3615 32℃   2011客户文章
    密度  g/mL 1.3534 42℃   2011客户文章
    密度  g/mL 1.3443 53℃   2011客户文章
    密度  g/mL 1.3361 63℃   2011客户文章
    热导率  W/(m.K) 0.145 293.00K   2014客户文章
    热分解onset温度  ℃ 421     2014客户文章
    热分解onset温度  ℃ 406     2015客户文章
    热分解peak温度  ℃ 461     2014客户文章
    热分解start温度  ℃ 329     2014客户文章
    熔点  ℃ 9    DSC/DTA  ILThermo
    粘度  cP 368.2 20℃   2011客户文章
    粘度  cP 274  25℃,101KPa  液体, Concentric cylinders viscometry  ILThermo
    粘度  cP 260.9 25℃   2011客户文章
    粘度  cP 168.6 32℃   2011客户文章
    粘度  cP 102.1 42℃   2011客户文章
    粘度  cP 71 53℃   2011客户文章
    粘度  cP 59.1 63℃   2011客户文章
    折光率   1.4094  25℃,101KPa  液体, Standard Abbe refractometry  ILThermo
    折光率   1.409     2012客户文章

  • 参考谱图

    1-丁基-3-甲基咪唑六氟磷酸盐,1-butyl-3-methylimidazolium hexafluorophosphate,BMImPF6,174501-64-5,核磁 NMR, H谱, 氘代丙酮
    1-丁基-3-甲基咪唑六氟磷酸盐,1-butyl-3-methylimidazolium hexafluorophosphate,BMImPF6,174501-64-5,核磁 NMR, H谱, 氘代丙酮
    1-丁基-3-甲基咪唑六氟磷酸盐,1-butyl-3-methylimidazolium hexafluorophosphate,BMImPF6,174501-64-5,核磁 NMR, C谱, 氘代丙酮
    1-丁基-3-甲基咪唑六氟磷酸盐,1-butyl-3-methylimidazolium hexafluorophosphate,BMImPF6,174501-64-5,核磁 NMR, C谱, 氘代丙酮
    1-丁基-3-甲基咪唑六氟磷酸盐,1-butyl-3-methylimidazolium hexafluorophosphate,BMImPF6,174501-64-5,NMR,H谱,CDCl3
    1-丁基-3-甲基咪唑六氟磷酸盐,1-butyl-3-methylimidazolium hexafluorophosphate,BMImPF6,174501-64-5,NMR,H谱,CDCl3
    Beniwal, Vijay; ChemPhysChem, (2015), 16(5), 1026-1034, CAplus

    1-丁基-3-甲基咪唑六氟磷酸盐,1-butyl-3-methylimidazolium hexafluorophosphate,BMImPF6,174501-64-5,NMR,H谱,氘代DMSO
    1-丁基-3-甲基咪唑六氟磷酸盐,1-butyl-3-methylimidazolium hexafluorophosphate,BMImPF6,174501-64-5,NMR,H谱,氘代DMSO
    Han, Feng; Organic & Biomolecular Chemistry, (2012), 10(2), 346-354, CAplus
    1-丁基-3-甲基咪唑六氟磷酸盐,1-butyl-3-methylimidazolium hexafluorophosphate,BMImPF6,174501-64-5,NMR,C谱,氘代DMSO
    1-丁基-3-甲基咪唑六氟磷酸盐,1-butyl-3-methylimidazolium hexafluorophosphate,BMImPF6,174501-64-5,NMR,C谱,氘代DMSO
    Han, Feng; Organic & Biomolecular Chemistry, (2012), 10(2), 346-354, CAplus

  • 安全信息

    Code
    Hazard Statement
    Source
    H413
    May cause long lasting harmful effects to aquatic life
    Expert Curated
    H335
    May cause respiratory irritation
    Alfa Aesar (a part of Thermo Fisher Scientific Chemicals, Inc.), European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most common notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, Fisher Scientific, Merck Life Science (Sigma-Aldrich)
    H333
    May be harmful if inhaled
    Expert Curated
    H319
    Causes serious eye irritation
    Alfa Aesar (a part of Thermo Fisher Scientific Chemicals, Inc.), European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most common notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, Fisher Scientific, Merck Life Science (Sigma-Aldrich), Merck Life Science OY (Sigma-Aldrich), Tokyo Chemical Industry Co (TCI America)
    H315
    Causes skin irritation
    Alfa Aesar (a part of Thermo Fisher Scientific Chemicals, Inc.), European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most common notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, Fisher Scientific, Merck Life Science (Sigma-Aldrich), Merck Life Science OY (Sigma-Aldrich), Tokyo Chemical Industry Co (TCI America)
    H302
    Harmful if swallowed
    Expert Curated

  • Other Names and Identifiers

    Canonical SMILES
    [F-][P+5]([F-])([F-])([F-])([F-])[F-].C1=C[N+](=CN1C)CCCC
    InChI
    InChI=1S/C8H15N2.F6P/c1-3-4-5-10-7-6-9(2)8-10;1-7(2,3,4,5)6/h6-8H,3-5H2,1-2H3;/q+1;-1
    InChI Key
    IXQYBUDWDLYNMA-UHFFFAOYSA-N
    19 Other Names for this Substance
    • 1H-Imidazolium, 1-butyl-3-methyl-, hexafluorophosphate(1-) (9CI)
    • 1-Butyl-3-methyl-1H-imidazolium hexafluorophosphate
    • 1-Butyl-3-methyl-1H-imidazolium hexafluorophosphate(1-)
    • 1-Butyl-3-methylimidazolinium hexafluorophosphate
    • 1-Butyl-3-methylimidazolium hexafluorophosphate
    • 1-Butyl-3-methylimidazolium hexafluorophosphate(1-)
    • 1-Methyl-3-butyl imidazolium hexafluorophosphate
    • 1-n-Butyl-3-methylimidazolium hexafluorophosphate
    • 3-Butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate
    • 3-Butyl-1-methylimidazolium hexafluorophosphate
    • [C4Mim+][PF6-]
    • A 33092
    • BMI-PF 6
    • Bmim hexafluorophosphate
    • Bmim hexafluorophosphate(1-)
    • BmimPF6
    • Butylmethylimidazolium hexafluorophosphate
    • LP 104
    • N-Butyl-N′-methylimidazolium hexafluorophosphate

  • 参考文献

    Experimental Properties

    Acoustic

    Biological

    Chemical

    Density

    Electrical

    Electronic

    Flow and Diffusion

    Interface

    Lipinski

    Mechanical

    Optical and Scattering

    Structure Related

    Thermal

    Experimental Spectra

    1H-NMR

    13C-NMR

    Additional Spectra

    hetero NMR

    IR

    Mass

    Raman

    UV and Visible

    X-Ray