1-己基-3-甲基咪唑四氟硼酸盐
1-hexyl-3-methylimidazolium tetrafluoroborate
- 分子式：C10H19BF4N2
- 分子量：254.08
- CAS编号：244193-50-8
- 纯度：98%
基本信息
| 产品名称： | 1-己基-3-甲基咪唑四氟硼酸盐 | ||
| 英文名称： | 1-hexyl-3-methylimidazolium tetrafluoroborate | ||
| CAS编号： | 244193-50-8 | 简 写： | HMImBF4 |
| 分 子 式 ： | C10H19BF4N2 | 分 子 量 ： | 254.08 |
| 纯 度： | 98% | 产品编号： | CP0116 |
物性数据
| 项目 | 数据 | 测试条件 | 备注 | 数据来源 |
| long-term热稳定性 ℃ | 203 | 2014客户文章 | ||
| 表面张力 mN/m | 41 | 298.15K | 2012客户文章 | |
| 表面张力 mN/m | 40.7 | 303.15K | 2012客户文章 | |
| 表面张力 mN/m | 40.3 | 308.15K | 2012客户文章 | |
| 表面张力 mN/m | 39.9 | 313.15K | 2012客户文章 | |
| 表面张力 mN/m | 39.4 | 318.15K | 2012客户文章 | |
| 表面张力 mN/m | 39 | 323.15K | 2012客户文章 | |
| 表面张力 mN/m | 38.6 | 328.15K | 2012客户文章 | |
| 表面张力 mN/m | 38.3 | 333.15K | 2012客户文章 | |
| 表面张力 mN/m | 38 | 338.15K | 2012客户文章 | |
| 表面张力 mN/m | 37.2 | 25℃,101KPa | 液体, Ring tensiometer | ILThermo |
| 电导率 mS/cm | 1.2 | 25℃,101KPa | 液体, Alternating current cell with electrodes | ILThermo |
| 电化学窗口 V | >4V | 2014年整理 | ||
| 密度 g/mL | 1.1463 | 298.15K | 2012客户文章 | |
| 密度 g/mL | 1.1451 | 25℃,101KPa | 液体, Vibrating tube method | ILThermo |
| 密度 g/mL | 1.1441 | 303.15K | 2012客户文章 | |
| 密度 g/mL | 1.142 | 308.15K | 2012客户文章 | |
| 密度 g/mL | 1.1403 | 313.15K | 2012客户文章 | |
| 密度 g/mL | 1.1383 | 318.15K | 2012客户文章 | |
| 密度 g/mL | 1.1361 | 323.15K | 2012客户文章 | |
| 密度 g/mL | 1.1345 | 328.15K | 2012客户文章 | |
| 密度 g/mL | 1.1322 | 333.15K | 2012客户文章 | |
| 密度 g/mL | 1.1302 | 338.15K | 2012客户文章 | |
| 热导率 W/(m.K) | 0.158 | 293.00K | 2014客户文章 | |
| 热分解onset温度 ℃ | 420 | 2014客户文章 | ||
| 热分解peak温度 ℃ | 465 | 2014客户文章 | ||
| 热分解start温度 ℃ | 332 | 2014客户文章 | ||
| 熔点 ℃ | -81 | 2014年整理 | ||
| 粘度 cP | 216 | 25℃,101KPa | 液体, Falling or rolling sphere viscometry | 2014整理 |
| 折光率 | 1.427 | 25℃,101KPa | 液体, Standard Abbe refractometry | ILThermo |
| 折光率 | 1.427 | 298.15K | 2012客户文章 | |
| 折光率 | 1.426 | 303.15K | 2012客户文章 | |
| 折光率 | 1.4249 | 308.15K | 2012客户文章 | |
| 折光率 | 1.4237 | 313.15K | 2012客户文章 | |
| 折光率 | 1.4226 | 318.15K | 2012客户文章 | |
| 折光率 | 1.4215 | 323.15K | 2012客户文章 | |
| 折光率 | 1.4204 | 328.15K | 2012客户文章 | |
| 折光率 | 1.4191 | 333.15K | 2012客户文章 | |
| 折光率 | 1.4179 | 338.15K | 2012客户文章 |
参考谱图
1-己基-3-甲基咪唑四氟硼酸盐,HMImBF4,244193-50-8,1-hexyl-3-methylimidazolium tetrafluoroborate,核磁 NMR, H谱, 氘代丙酮
1-己基-3-甲基咪唑四氟硼酸盐,HMImBF4,244193-50-8,1-hexyl-3-methylimidazolium tetrafluoroborate,核磁 NMR, C谱, 氘代丙酮
1-己基-3-甲基咪唑四氟硼酸盐,HMImBF4,244193-50-8,1-hexyl-3-methylimidazolium tetrafluoroborate,核磁 NMR, H谱, CD2Cl2
Srour, Hassan; Green Chemistry, (2013), 15(5), 1341-1347, CAplus
1-己基-3-甲基咪唑四氟硼酸盐,HMImBF4,244193-50-8,1-hexyl-3-methylimidazolium tetrafluoroborate,核磁 NMR, C谱, CD2Cl2
Srour, Hassan; Green Chemistry, (2013), 15(5), 1341-1347, CAplus
1-己基-3-甲基咪唑四氟硼酸盐,HMImBF4,244193-50-8,1-hexyl-3-methylimidazolium tetrafluoroborate,核磁 NMR, F谱, CD2Cl2
Srour, Hassan; Green Chemistry, (2013), 15(5), 1341-1347, CAplus
1-己基-3-甲基咪唑四氟硼酸盐,HMImBF4,244193-50-8,1-hexyl-3-methylimidazolium tetrafluoroborate,核磁 NMR, B谱, CD2Cl2
Srour, Hassan; Green Chemistry, (2013), 15(5), 1341-1347, CAplus
1-己基-3-甲基咪唑四氟硼酸盐,HMImBF4,244193-50-8,1-hexyl-3-methylimidazolium tetrafluoroborate,ESI-MS
Srour, Hassan; Green Chemistry, (2013), 15(5), 1341-1347, CAplus
安全信息
| Code |
Hazard Statement |
Source |
| H335 |
May cause respiratory irritation |
Expert Curated |
| H319 |
Causes serious eye irritation |
European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated |
| H318 |
Causes serious eye damage |
European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria |
| H315 |
Causes skin irritation |
European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated |
| H314 |
Causes severe skin burns and eye damage |
European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria |
| H303 |
May be harmful if swallowed |
Expert Curated |
| H302 |
Harmful if swallowed |
European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria |
Other Names and Identifiers
Canonical SMILES
[F-][B+3]([F-])([F-])[F-].C1=C[N+](=CN1C)CCCCCC
InChI
InChI=1S/C10H19N2.BF4/c1-3-4-5-6-7-12-9-8-11(2)10-12;2-1(3,4)5/h8-10H,3-7H2,1-2H3;/q+1;-1
InChI Key
MFXLOVLEQJRXFP-UHFFFAOYSA-N
8 Other Names for this Substance
- 1H-Imidazolium, 1-hexyl-3-methyl-, tetrafluoroborate(1-) (9CI)
- 1-Hexyl-3-methyl-1H-imidazolium tetrafluoroborate
- 1-Hexyl-3-methyl-1H-imidazolium tetrafluoroborate(1-)
- 1-Hexyl-3-methylimidazolium tetrafluoroborate
- 1-Hexyl-3-methylimidazolium tetrafluoroborate(1-)
- 1-Methyl-3-hexylimidazolium tetrafluoroborate
- 1-n-Hexyl-3-ethylimidazolium tetrafluoroborate
- 1-n-Hexyl-3-methylimidazolium tetrafluoroborate
参考文献
Experimental Properties
Biological
Chemical
Density
- (1) Zhou, Zhi-Bin; Chemistry - A European Journal, (2004), 10(24), 6581-6591, CAplus
- (2) Moganty, Surya S.; Industrial & Engineering Chemistry Research, (2010), 49(19), 9370-9376, CAplus
- (3) Bogdanov, Milen G.; Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences, (2009), 64(2), 215-222, CAplus
- (4) Fernandez-Navarro, J. J.; Journal of Chromatography A, (2011), 1218(3), 398-407, CAplus
- (5) Ruiz-Angel, Maria Jose; Journal of Chromatography A, (2006), 1113(1-2), 101-108, CAplus
- (6) Rilo, Esther; Journal of Chemical & Engineering Data, (2010), 55(2), 639-644, CAplus
- (7) Li, Xingang; Energy & Fuels, (2016), 30(9), 7074-7081, CAplus
- (8) Shirota, Hideaki; Journal of Chemical & Engineering Data, (2011), 56(5), 2453-2459, CAplus
- (9) Sanmamed, Y. A.; Fluid Phase Equilibria, (2007), 252(1-2), 96-102, CAplus
- (10) Taguchi, Ryosuke; Journal of Chemical & Engineering Data, (2009), 54(1), 22-27, CAplus
- (11) Muhammad, Ayyaz; Journal of Chemical Thermodynamics, (2008), 40(9), 1433-1438, CAplus
- (12) Garcia-Miaja, Gonzalo; Fluid Phase Equilibria, (2008), 274(1-2), 59-67, CAplus
- (13) Garcia-Miaja, Gonzalo; Journal of Chemical Thermodynamics, (2009), 41(3), 334-341, CAplus
- (14) Sanmamed, Y. A.; Journal of Chemical Thermodynamics, (2010), 42(4), 553-563, CAplus
- (15) Safarov, Javid; Journal of Molecular Liquids, (2010), 153(2-3), 153-158, CAplus
- (16) Vakili-Nezhaad, Gholamreza; Journal of Chemical Thermodynamics, (2012), 54, 148-154, CAplus
- (17) Ning, Hui; Science China: Chemistry, (2012), 55(8), 1509-1518, CAplus
- (18) Miran Beigi, Ali Akbar; Journal of Molecular Liquids, (2013), 177, 361-368, CAplus
- (19) Nakamura, Kenji; ChemPhysChem, (2010), 11(1), 285-294, CAplus
- (20) Slattery, John M.; Angewandte Chemie, International Edition, (2007), 46(28), 5384-5388, CAplus
- (21) Mendez-Morales, T.; Journal of Physical Chemistry B, (2011), 115(38), 11170-11182, CAplus
Electrical
- (1) Nakamura, Kenji; ChemPhysChem, (2010), 11(1), 285-294, CAplus
- (2) Fawcett, W. Ronald; Journal of Electroanalytical Chemistry, (2011), 660(2), 230-233, CAplus
- (3) Alam, Muhammad Tanzirul; Journal of Physical Chemistry C, (2008), 112(42), 16600-16608, CAplus
- (4) Stoppa, Alexander; Journal of Physical Chemistry B, (2008), 112(16), 4854-4858, CAplus
- (5) Vila, J.; Electrochimica Acta, (2007), 52(26), 7413-7417, CAplus
- (6) Leys, Jan; Journal of Chemical Physics, (2008), 128(6), 064509/1-064509/7, CAplus
- (7) Gonzalez, P.; Journal of the Chilean Chemical Society, (2010), 55(2), 274-277, CAplus
- (8) Fawcett, W. Ronald; Journal of Electroanalytical Chemistry, (2011), 660(2), 230-233, CAplus
- (9) Ning, Hui; Science China: Chemistry, (2012), 55(8), 1509-1518, CAplus
- (10) Slattery, John M.; Angewandte Chemie, International Edition, (2007), 46(28), 5384-5388, CAplus
- (11) Rilo, Esther; Journal of Chemical & Engineering Data, (2010), 55(2), 639-644, CAplus
Flow and Diffusion
- (1) Sanmamed, Y. A.; Fluid Phase Equilibria, (2007), 252(1-2), 96-102, CAplus
- (2) Muhammad, Ayyaz; Journal of Chemical Thermodynamics, (2008), 40(9), 1433-1438, CAplus
- (3) Sanmamed, Y. A.; Journal of Chemical Thermodynamics, (2010), 42(4), 553-563, CAplus
- (4) Khupse, Nageshwar D.; Indian Journal of Chemistry, Section A: Inorganic, Bio-inorganic, Physical, Theoretical & Analytical Chemistry, (2010), 49A(5-6), 727-730, CAplus
- (5) Fawcett, W. Ronald; Journal of Electroanalytical Chemistry, (2011), 660(2), 230-233, CAplus
- (6) Flieger, Jolanta; Journal of Separation Science, (2012), 35(2), 248-255, CAplus
- (7) Vakili-Nezhaad, Gholamreza; Journal of Chemical Thermodynamics, (2012), 54, 148-154, CAplus
- (8) Ning, Hui; Science China: Chemistry, (2012), 55(8), 1509-1518, CAplus
- (9) Miran Beigi, Ali Akbar; Journal of Molecular Liquids, (2013), 177, 361-368, CAplus
- (10) Nakamura, Kenji; ChemPhysChem, (2010), 11(1), 285-294, CAplus
- (11) Zhou, Zhi-Bin; Chemistry - A European Journal, (2004), 10(24), 6581-6591, CAplus
- (12) Strehmel, Veronika; ACS Symposium Series, (2005), 913, 17-36, CAplus
- (13) Slattery, John M.; Angewandte Chemie, International Edition, (2007), 46(28), 5384-5388, CAplus
- (14) Bogdanov, Milen G.; Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences, (2009), 64(2), 215-222, CAplus
- (15) Rilo, Esther; Journal of Chemical & Engineering Data, (2010), 55(2), 639-644, CAplus
- (16) Zimmermann, Johannes; Organic Process Research & Development, (2010), 14(5), 1102-1109, CAplus
- (17) Moganty, Surya S.; Industrial & Engineering Chemistry Research, (2010), 49(19), 9370-9376, CAplus
- (18) Shirota, Hideaki; Journal of Chemical & Engineering Data, (2011), 56(5), 2453-2459, CAplus
Interface
- (1) Ghatee, Mohammad Hadi; Fluid Phase Equilibria, (2008), 263(2), 168-175, CAplus
- (2) Muhammad, Ayyaz; Journal of Chemical Thermodynamics, (2008), 40(9), 1433-1438, CAplus
- (3) Wang, Jian-Ying; Huaxue Xuebao, (2007), 65(15), 1443-1448, CAplus
- (4) Vakili-Nezhaad, Gholamreza; Journal of Chemical Thermodynamics, (2012), 54, 148-154, CAplus
- (5) Miran Beigi, Ali Akbar; Journal of Molecular Liquids, (2013), 177, 361-368, CAplus
- (6) Rollins, Julie B.; Journal of Physical Chemistry B, (2007), 111(18), 4990-4999, CAplus
- (7) Shirota, Hideaki; Journal of Chemical & Engineering Data, (2011), 56(5), 2453-2459, CAplus
Mechanical
Optical and Scattering
Structure Related
Thermal
- (1) Zhou, Zhi-Bin; Chemistry - A European Journal, (2004), 10(24), 6581-6591, CAplus
- (2) Strehmel, Veronika; ACS Symposium Series, (2005), 913, 17-36, CAplus
- (3) Fernandez-Navarro, J. J.; Journal of Chromatography A, (2011), 1218(3), 398-407, CAplus
- (4) Ruiz-Angel, Maria Jose; Journal of Chromatography A, (2006), 1113(1-2), 101-108, CAplus
- (5) Flieger, Jolanta; Journal of Separation Science, (2012), 35(2), 248-255, CAplus
- (6) Glasser, Leslie; Thermochimica Acta, (2004), 421(1-2), 87-93, CAplus
- (7) Wang, Jian-Ying; Huaxue Xuebao, (2007), 65(15), 1443-1448, CAplus
- (8) Vakili-Nezhaad, Gholamreza; Journal of Chemical Thermodynamics, (2012), 54, 148-154, CAplus
- (9) Glasser, Leslie; Thermochimica Acta, (2004), 421(1-2), 87-93, CAplus
- (10) Garcia-Miaja, Gonzalo; Fluid Phase Equilibria, (2008), 274(1-2), 59-67, CAplus
- (11) Garcia-Miaja, Gonzalo; Journal of Chemical Thermodynamics, (2009), 41(3), 334-341, CAplus
- (12) Waliszewski, Dariusz; Journal of Chemical Thermodynamics, (2009), 42(2), 189-192, CAplus
- (13) Safarov, Javid; Journal of Molecular Liquids, (2010), 153(2-3), 153-158, CAplus
- (14) Muhammad, Ayyaz; Journal of Chemical Thermodynamics, (2008), 40(9), 1433-1438, CAplus
- (15) Zhou, Zhi-Bin; Chemistry - A European Journal, (2004), 10(24), 6581-6591, CAplus
- (16) Zimmermann, Johannes; Organic Process Research & Development, (2010), 14(5), 1102-1109, CAplus
- (17) Nieto de Castro, C. A.; Journal of Chemical & Engineering Data, (2010), 55(2), 653-661, CAplus
- (18) Muhammad, Ayyaz; Journal of Chemical Thermodynamics, (2008), 40(9), 1433-1438, CAplus
- (19) Safarov, Javid; Journal of Molecular Liquids, (2010), 153(2-3), 153-158, CAplus
- (20) Vakili-Nezhaad, Gholamreza; Journal of Chemical Thermodynamics, (2012), 54, 148-154, CAplus
- (21) Miran Beigi, Ali Akbar; Journal of Molecular Liquids, (2013), 177, 361-368, CAplus
Experimental Spectra
1H-NMR
- (1) Hodyna, Diana; Chemical Biology & Drug Design, (2016), 88(3), 422-433, CAplus
- (2) Malek, Naved I.; Journal of Chemical & Engineering Data, (2014), 59(3), 540-553, CAplus
- (3) Thanikachalam, Venugopal; Journal of Materials Chemistry C: Materials for Optical and Electronic Devices, (2020), 8(8), 2899-2912, CAplus
- (4) Grommet, Angela B.; Journal of the American Chemical Society, (2017), 139(6), 2176-2179, CAplus
- (5) Fatyeyeva, Kateryna; Reactive & Functional Polymers, (2018), 130, 16-28, CAplus
- (6) Srour, Hassan; Green Chemistry, (2013), 15(5), 1341-1347, CAplus
- (7) Wang, Ruifeng; Journal of Molecular Liquids, (2016), 221, 339-345, CAplus
- (8) Paterno, Alessio; RSC Advances, (2016), 6(42), 36085-36089, CAplus
- (9) Miran Beigi, Ali Akbar; Journal of Molecular Liquids, (2013), 177, 361-368, CAplus
- (10) Ben Ghanem, Ouahid; Journal of Hazardous Materials, (2015), 297, 198-206, CAplus
- (11) Xu, Dan-Qian; Journal of Molecular Catalysis A: Chemical, (2005), 235(1-2), 137-142, CAplus
- (12) Bravo, Jose Luis; Ultrasonics Sonochemistry, (2006), 13(5), 408-414, CAplus
- (13) Shirota, Hideaki; Journal of Chemical & Engineering Data, (2011), 56(5), 2453-2459, CAplus
13C-NMR
- (1) Thanikachalam, Venugopal; Journal of Materials Chemistry C: Materials for Optical and Electronic Devices, (2020), 8(8), 2899-2912, CAplus
- (2) Srour, Hassan; Green Chemistry, (2013), 15(5), 1341-1347, CAplus
- (3) Paterno, Alessio; RSC Advances, (2016), 6(42), 36085-36089, CAplus
- (4) Bravo, Jose Luis; Ultrasonics Sonochemistry, (2006), 13(5), 408-414, CAplus
Additional Spectra
hetero NMR
IR
- (1) Singh, Prabhat K.; Journal of Photochemistry and Photobiology, A: Chemistry, (2012), 246, 16-22, CAplus
- (2) Xu, Dan-Qian; Journal of Molecular Catalysis A: Chemical, (2005), 235(1-2), 137-142, CAplus
- (3) Bravo, Jose Luis; Ultrasonics Sonochemistry, (2006), 13(5), 408-414, CAplus
- (4) Rollins, Julie B.; Journal of Physical Chemistry B, (2007), 111(18), 4990-4999, CAplus
- (5) MacMillan, Amanda C.; Journal of Physical Chemistry C, (2014), 118(50), 29458-29466, CAplus
Mass
UV and Visible
- (1) Singh, Prabhat K.; Journal of Photochemistry and Photobiology, A: Chemistry, (2012), 246, 16-22, CAplus
- (2) Ghosh, Anup; Journal of Physical Chemistry C, (2014), 118(9), 5051-5057, CAplus
- (3) Ghosh, Anup; Journal of Physical Chemistry C, (2014), 118(9), 5051-5057, CAplus
- (4) Marszall, Michal Piotr; Journal of Separation Science, (2006), 29(8), 1138-1145, CAplus
