四甲基氯化铵
Tetramethylammonium chloride
- 分子式:C4H12ClN
- 分子量:109.6
- CAS编号:75-57-0
- 纯度:99%
基本信息
物性数据
参考谱图
安全信息
Code |
Hazard Statement |
Source |
H411 |
Toxic to aquatic life with long lasting effects |
European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, Korea (South) Chemicals Control Act - GHS Classification&Labelling of Toxic Chemicals, Merck Life Science (Sigma-Aldrich), Sigma-Aldrich (Merck), Sigma-Aldrich (as MiliporeSigma, Merck) |
H410 |
Very toxic to aquatic life with long lasting effects |
European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria |
H401 |
Toxic to aquatic life |
Sigma-Aldrich (as MiliporeSigma, Merck) |
H400 |
Very toxic to aquatic life |
Expert Curated |
H373 |
May cause damage to organs; through prolonged or repeated exposure |
Expert Curated, Japan GHS Classifications (Japanese) |
H372 |
Causes damage to organs through prolonged or repeated exposure |
Expert Curated, Japan GHS Classifications (Japanese) |
H370 |
Causes damage to organs |
Alfa Aesar (a part of Thermo Fisher Scientific Chemicals, Inc.), European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, Fisher Scientific, Japan GHS Classifications (Japanese), Life Technologies (a part of Thermo Fisher Scientific), MP Biomedicals, Merck Life Science (Sigma-Aldrich), Sigma-Aldrich (Merck), Sigma-Aldrich (as MiliporeSigma, Merck) |
H335 |
May cause respiratory irritation |
Affymetrix (a part of Thermo Fisher Scientific), European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated |
H319 |
Causes serious eye irritation |
Affymetrix (a part of Thermo Fisher Scientific), Alfa Aesar (a part of Thermo Fisher Scientific Chemicals, Inc.), European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria |
H318 |
Causes serious eye damage |
Expert Curated, Fisher Scientific, Life Technologies (a part of Thermo Fisher Scientific) |
H315 |
Causes skin irritation |
Affymetrix (a part of Thermo Fisher Scientific), Alfa Aesar (a part of Thermo Fisher Scientific Chemicals, Inc.), BDH, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, Fisher Scientific, Japan GHS Classifications (Japanese), Korea (South) Chemicals Control Act - GHS Classification&Labelling of Toxic Chemicals, Life Technologies (a part of Thermo Fisher Scientific), MP Biomedicals, Merck Life Science (Sigma-Aldrich), Sigma-Aldrich (Merck), Sigma-Aldrich (as MiliporeSigma, Merck) |
H312 |
Harmful in contact with skin |
BDH, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, New Zealand Hazardous Substances and New Organisms (HSNO) Act - Classification of Chemicals |
H311 |
Toxic in contact with skin |
Affymetrix (a part of Thermo Fisher Scientific), Alfa Aesar (a part of Thermo Fisher Scientific Chemicals, Inc.), European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, Fisher Scientific, Japan GHS Classifications (Japanese), Korea (South) Chemicals Control Act - GHS Classification&Labelling of Toxic Chemicals, Life Technologies (a part of Thermo Fisher Scientific), MP Biomedicals, Merck Life Science (Sigma-Aldrich), New Zealand Hazardous Substances and New Organisms (HSNO) Act - Classification of Chemicals, Sigma-Aldrich (Merck), Sigma-Aldrich (as MiliporeSigma, Merck) |
H302 |
Harmful if swallowed |
Affymetrix (a part of Thermo Fisher Scientific) |
H301 |
Toxic if swallowed |
European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, Japan GHS Classifications (Japanese), New Zealand Hazardous Substances and New Organisms (HSNO) Act - Classification of Chemicals |
H300 |
Fatal if swallowed |
Alfa Aesar (a part of Thermo Fisher Scientific Chemicals, Inc.), European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, Fisher Scientific, Korea (South) Chemicals Control Act - GHS Classification&Labelling of Toxic Chemicals, Life Technologies (a part of Thermo Fisher Scientific), MP Biomedicals, Merck Life Science (Sigma-Aldrich), Sigma-Aldrich (Merck), Sigma-Aldrich (as MiliporeSigma, Merck) |
Other Names and Identifiers
Canonical SMILES
[Cl-].C[N+](C)(C)C
InChI
InChI=1S/C4H12N.ClH/c1-5(2,3)4;/h1-4H3;1H/q+1;/p-1
InChI Key
OKIZCWYLBDKLSU-UHFFFAOYSA-M
6 Other Names for this Substance
- Ammonium, tetramethyl-, chloride (8CI)
- Methanaminium, N,N,N-trimethyl-, chloride (9CI)
- Tetramethylammonium chloride (6CI)
- Tetramine
- Tetramine chloride
- TMAC 100
参考文献
Experimental Properties
Chemical
Density
(1) "International Chemical Safety Cards" data were obtained from the National Institute for Occupational Safety and Health (US)
Flow and Diffusion
Interface
Structure Related
Thermal
- (1) Rassow, Hermann; Zeitschrift fuer Anorganische und Allgemeine Chemie, (1920), 114, 117-50, CAplus
- (2) "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US)
- (3) "International Chemical Safety Cards" data were obtained from the National Institute for Occupational Safety and Health (US)
- (4) BE637992, 1964, CAplus
- (5) Kabachnik, M. I.; Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, (1989)(12), 2789-92, CAplus
- (6) Horner, L.; Justus Liebigs Annalen der Chemie, (1955), 597, 20-47, CAplus
- (7) Shamsuri, Ahmad Adlie; International Journal of Chemistry (Toronto, ON, Canada), (2011), 3(1), 161-165, CAplus
- (8) Rudchenko, V. F.; Tetrahedron, (1988), 44(8), 2233-9, CAplus
- (9) Jung, Michael E.; Tetrahedron Letters, (1988), 29(3), 297-300, CAplus
- (10) Qiu, Jianghua; Fuel Processing Technology, (2009), 90(12), 1538-1542, CAplus
- (11) Polezhaeva, N. I.; Russian Journal of Applied Chemistry, (2006), 79(9), 1559-1560, CAplus
Experimental Spectra
1H-NMR
- (1) Sigma-Aldrich Co. LLC. (Spectral Data were obtained from John Wiley & Sons, Inc.)
- (2) Copyright Bio-Rad Laboratories. All Rights Reserved.
- (3) Sigma-Aldrich (Spectral data were obtained from Advanced Chemistry Development, Inc.)
- (4) Bartoli, Sandra; Journal of the American Chemical Society, (2002), 124(28), 8307-8315, CAplus
- (5) Atwood, Jerry L.; Chemical Communications (Cambridge, United Kingdom), (2003)(8), 940-941, CAplus
- (6) Mahnke, Devin J.; Chemical Communications (Cambridge, United Kingdom), (2007)(36), 3738-3740, CAplus
- (7) Rudchenko, V. F.; Tetrahedron, (1988), 44(8), 2233-9, CAplus
13C-NMR
- (1) Spectral data were obtained from John Wiley & Sons, Inc.
- (2) Copyright Bio-Rad Laboratories. All Rights Reserved.
- (3) Sigma-Aldrich (Spectral data were obtained from Advanced Chemistry Development, Inc.)
IR
- (1) Spectral data were obtained from John Wiley & Sons, Inc.
- (2) Sigma-Aldrich Co. LLC. (Spectral Data were obtained from John Wiley & Sons, Inc.)
- (3) Copyright Bio-Rad Laboratories. All Rights Reserved.
- (4) "Integrated Spectral Data Base System of Organic Compounds" data were obtained from the National Institute of Advanced Industrial Science and Technology (Japan)
- (5) Guo, Wujie; Green Chemistry, (2013), 15(1), 226-229, CAplus
Raman
- (1) Sigma-Aldrich Co. LLC. (Spectral Data were obtained from John Wiley & Sons, Inc.)
- (2) Copyright Bio-Rad Laboratories. All Rights Reserved.
- (3) "Integrated Spectral Data Base System of Organic Compounds" data were obtained from the National Institute of Advanced Industrial Science and Technology (Japan)
- (4) Hidaka, Fumi; Chemical Physics Letters, (2003), 379(3,4), 216-222, CAplus