四甲基溴化铵
tetramethylammomium bromide
- 分子式：C4H12BrN
- 分子量：154.05
- CAS编号：64-20-0
- 纯度：99%
基本信息
物性数据
参考谱图
安全信息
| Code |
Hazard Statement |
Source |
| H400 |
Very toxic to aquatic life |
Expert Curated |
| H335 |
May cause respiratory irritation |
Alfa Aesar (a part of Thermo Fisher Scientific Chemicals, Inc.), European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most common notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated |
| H319 |
Causes serious eye irritation |
Alfa Aesar (a part of Thermo Fisher Scientific Chemicals, Inc.), European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most common notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria |
| H318 |
Causes serious eye damage |
Expert Curated |
| H315 |
Causes skin irritation |
Alfa Aesar (a part of Thermo Fisher Scientific Chemicals, Inc.), European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most common notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated |
| H313 |
May be harmful in contact with skin |
Expert Curated |
| H301 |
Toxic if swallowed |
European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated |
| H300 |
Fatal if swallowed |
Alfa Aesar (a part of Thermo Fisher Scientific Chemicals, Inc.), European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most common notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Merck Life Science OY (Sigma-Aldrich) |
Other Names and Identifiers
Canonical SMILES
[Br-].C[N+](C)(C)C
InChI
InChI=1S/C4H12N.BrH/c1-5(2,3)4;/h1-4H3;1H/q+1;/p-1
InChI Key
DDFYFBUWEBINLX-UHFFFAOYSA-M
5 Other Names for this Substance
- Ammonium, tetramethyl-, bromide (8CI)
- Methanaminium, N,N,N-trimethyl-, bromide (9CI)
- Methyl, (dimethylamino)-, methobromide (7CI)
- Tetramethylammonium bromide (6CI)
- TMAB
参考文献
Experimental Properties
Chemical
Flow and Diffusion
Interface
Thermal
- (1) "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US)
- (2) Abramyan, T. D.; Zhurnal Obshchei Khimii, (1989), 59(3), 564-7, CAplus
- (3) Jung, Michael E.; Tetrahedron Letters, (1988), 29(3), 297-300, CAplus
Experimental Spectra
1H-NMR
- (1) Sigma-Aldrich Co. LLC. (Spectral Data were obtained from John Wiley & Sons, Inc.)
- (2) Denmark, Scott E.; Journal of the American Chemical Society, (2012), 134(32), 13415-13429, CAplus
- (3) Copyright Bio-Rad Laboratories. All Rights Reserved.
- (4) Sigma-Aldrich (Spectral data were obtained from Advanced Chemistry Development, Inc.)
- (5) Atwood, Jerry L.; Chemical Communications (Cambridge, United Kingdom), (2003)(8), 940-941, CAplus
- (6) Bielejewski, Michal; Journal of Magnetic Resonance, (2014), 243, 17-24, CAplus
- (7) Mondal, Anirban; Journal of Physical Chemistry B, (2015), 119(5), 1994-2002, CAplus
- (8) Cabaleiro-Lago, Celia; Langmuir, (2005), 21(25), 11637-11644, CAplus
- (9) Zheng, Zhuoqun; Chemical Communications (Cambridge, United Kingdom), (2006)(17), 1864-1865, CAplus
13C-NMR
- (1) Sigma-Aldrich Co. LLC. (Spectral Data were obtained from John Wiley & Sons, Inc.)
- (2) Denmark, Scott E.; Journal of the American Chemical Society, (2012), 134(32), 13415-13429, CAplus
- (3) Copyright Bio-Rad Laboratories. All Rights Reserved.
- (4) Sigma-Aldrich (Spectral data were obtained from Advanced Chemistry Development, Inc.)
IR
- (1) Sigma-Aldrich Co. LLC. (Spectral Data were obtained from John Wiley & Sons, Inc.)
- (2) Copyright Bio-Rad Laboratories. All Rights Reserved.
- (3) "Integrated Spectral Data Base System of Organic Compounds" data were obtained from the National Institute of Advanced Industrial Science and Technology (Japan)
- (4) Spinner, E.; Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy, (2003), 59A(7), 1441-1456, CAplus
- (5) Burnett, Andrew D.; Analytical Chemistry (Washington, DC, United States), (2013), 85(16), 7926-7934, CAplus
- (6) Mondal, Anirban; Journal of Physical Chemistry B, (2015), 119(5), 1994-2002, CAplus
Mass
(1) Spectral data were obtained from John Wiley & Sons, Inc.
Raman
- (1) Sigma-Aldrich Co. LLC. (Spectral Data were obtained from John Wiley & Sons, Inc.)
- (2) "Integrated Spectral Data Base System of Organic Compounds" data were obtained from the National Institute of Advanced Industrial Science and Technology (Japan)
- (3) Spinner, E.; Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy, (2003), 59A(7), 1457-1468, CAplus
- (4) Spinner, E.; Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy, (2003), 59A(7), 1441-1456, CAplus
