四甲基氢氧化铵
tetramethylammomium hydroxide
- 分子式:C4H23NO6
- 分子量:181.23
- CAS编号:75-59-2
- 纯度:50%
基本信息
物性数据
参考谱图
安全信息
Code |
Hazard Statement |
Source |
H413 |
May cause long lasting harmful effects to aquatic life |
European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria |
H412 |
Harmful to aquatic life with long lasting effects |
European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, New Zealand Hazardous Substances and New Organisms (HSNO) Act - Classification of Chemicals, Penta International |
H411 |
Toxic to aquatic life with long lasting effects |
Acros Organics (part of Thermo Fisher Scientific), Carlo Erba Reagents, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, Korea (South) Chemicals Control Act - GHS Classification&Labelling of Toxic Chemicals, Pfaltz&Bauer |
H402 |
Harmful to aquatic life |
Penta International |
H401 |
Toxic to aquatic life |
China Classification Information Sheet of Hazardous Chemicals (Draft), Expert Curated, Shanghai Aladdin Biochemical Technology, Sigma-Aldrich (as MiliporeSigma, Merck) |
H400 |
Very toxic to aquatic life |
European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated |
H372 |
Causes damage to organs through prolonged or repeated exposure |
Acros Organics (Fisher Scientific), Acros Organics (part of Thermo Fisher Scientific), Alfa Aesar (a part of Thermo Fisher Scientific Chemicals, Inc.), Carlo Erba Reagents, China Classification Information Sheet of Hazardous Chemicals (Draft), European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, Fisher Scientific, Japan GHS Classifications (Japanese), Sigma-Aldrich (as MiliporeSigma, Merck), TCI America, Tokyo Chemical Industry Co (TCI America) |
H371 |
May cause damage to organs |
Acros Organics (Fisher Scientific) |
H370 |
Causes damage to organs |
Acros Organics (part of Thermo Fisher Scientific), Alfa Aesar (a part of Thermo Fisher Scientific Chemicals, Inc.), Carlo Erba Reagents, China Classification Information Sheet of Hazardous Chemicals (Draft), European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, Fisher Scientific, Japan GHS Classifications (Japanese), Sigma-Aldrich (as MiliporeSigma, Merck), TCI America, Tokyo Chemical Industry Co (TCI America) |
H335 |
May cause respiratory irritation |
Acros Organics (Fisher Scientific), Alfa Aesar (a part of Thermo Fisher Scientific Chemicals, Inc.), European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Pfaltz&Bauer |
H332 |
Harmful if inhaled |
European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, Pfaltz&Bauer |
H331 |
Toxic if inhaled |
European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria |
H330 |
Fatal if inhaled |
Shanghai Aladdin Biochemical Technology |
H318 |
Causes serious eye damage |
Acros Organics (Fisher Scientific), Acros Organics (part of Thermo Fisher Scientific), Alfa Aesar (a part of Thermo Fisher Scientific Chemicals, Inc.), Carlo Erba Reagents, China Classification Information Sheet of Hazardous Chemicals (Draft), European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, Fisher Scientific, Japan GHS Classifications (Japanese), New Zealand Hazardous Substances and New Organisms (HSNO) Act - Classification of Chemicals, Penta International, Pfaltz&Bauer, Shanghai Aladdin Biochemical Technology, Sigma-Aldrich (Merck), Sigma-Aldrich (as MiliporeSigma, Merck), TCI America, Tokyo Chemical Industry Co (TCI America) |
H314 |
Causes severe skin burns and eye damage |
Acros Organics (Fisher Scientific), Acros Organics (part of Thermo Fisher Scientific), Alfa Aesar (a part of Thermo Fisher Scientific Chemicals, Inc.), Carlo Erba Reagents, China Classification Information Sheet of Hazardous Chemicals (Draft), European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most common notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, Fisher Scientific, Japan GHS Classifications (Japanese), Korea (South) Chemicals Control Act - GHS Classification&Labelling of Toxic Chemicals, New Zealand Hazardous Substances and New Organisms (HSNO) Act - Classification of Chemicals, Penta International, Pfaltz&Bauer, Shanghai Aladdin Biochemical Technology, Sigma-Aldrich (Merck), Sigma-Aldrich (as MiliporeSigma, Merck), TCI America, Tokyo Chemical Industry Co (TCI America) |
H312 |
Harmful in contact with skin |
European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Tokyo Chemical Industry Co (TCI America) |
H311 |
Toxic in contact with skin |
European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most common notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Sigma-Aldrich (Merck) |
H310 |
Fatal in contact with skin |
Acros Organics (Fisher Scientific), Acros Organics (part of Thermo Fisher Scientific), Alfa Aesar (a part of Thermo Fisher Scientific Chemicals, Inc.), Carlo Erba Reagents, China Classification Information Sheet of Hazardous Chemicals (Draft), European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, Fisher Scientific, Japan GHS Classifications (Japanese), Korea (South) Chemicals Control Act - GHS Classification&Labelling of Toxic Chemicals, Pfaltz&Bauer, Sigma-Aldrich (as MiliporeSigma, Merck) |
H302 |
Harmful if swallowed |
Acros Organics (part of Thermo Fisher Scientific), Expert Curated, New Zealand Hazardous Substances and New Organisms (HSNO) Act - Classification of Chemicals, Tokyo Chemical Industry Co (TCI America) |
H301 |
Toxic if swallowed |
European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, Penta International |
H300+H310 |
Fatal if swallowed or in contact with skin |
TCI America |
H300 |
Fatal if swallowed |
Acros Organics (part of Thermo Fisher Scientific), Alfa Aesar (a part of Thermo Fisher Scientific Chemicals, Inc.), Carlo Erba Reagents, China Classification Information Sheet of Hazardous Chemicals (Draft), European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, Fisher Scientific, Japan GHS Classifications (Japanese), Korea (South) Chemicals Control Act - GHS Classification&Labelling of Toxic Chemicals, Pfaltz&Bauer, Shanghai Aladdin Biochemical Technology, Sigma-Aldrich (Merck), Sigma-Aldrich (as MiliporeSigma, Merck) |
H290 |
May be corrosive to metals |
European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria |
H226 |
Flammable liquid and vapour |
European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria |
H224 |
Extremely flammable liquid and vapour |
European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria |
Other Names and Identifiers
Canonical SMILES
[OH-].C[N+](C)(C)C
InChI
InChI=1S/C4H12N.H2O/c1-5(2,3)4;/h1-4H3;1H2/q+1;/p-1
InChI Key
WGTYBPLFGIVFAS-UHFFFAOYSA-M
39 Other Names for this Substance
- Ammonium, tetramethyl-, hydroxide (8CI)
- Methanaminium, N,N,N-trimethyl-, hydroxide (9CI)
- Tetramethylammonium hydroxide (6CI)
- AR 300-49
- AZ 300MIF
- AZ 726
- AZ 726MIF
- AZ-MIF 300
- CD 26
- CPD 18
- L 09658
- LDD 26
- LDD 26W
- Megaposit CD 14
- Megaposit MF 24A
- MF 24A
- MF 319
- MF 321
- MF-CD 26
- Microposit CD 26
- Microposit MF 319
- Microposit MF 321
- Microposit MF-CD 26
- MIF 726
- NMD 3
- NMW-W
- OCG 934
- OCG 945
- OCG-OPD 262
- OPD 262
- OPD 5262
- Photoresist ma-D 525
- PRS 2000
- RD 6
- RD 6 (developer)
- TMAH
- TMAH 25
- Tokuso SD 20
- Tokuso SD 25
参考文献
Experimental Spectra
1H-NMR
13C-NMR
- (1) Copyright Bio-Rad Laboratories. All Rights Reserved.
- (2) Mihailova, B.; Journal of Physical Chemistry B, (2005), 109(36), 17060-17065, CAplus
hetero NMR
IR
- (1) Sigma-Aldrich Co. LLC. (Spectral Data were obtained from John Wiley & Sons, Inc.)
- (2) "Integrated Spectral Data Base System of Organic Compounds" data were obtained from the National Institute of Advanced Industrial Science and Technology (Japan)
- (3) Ghammamy, S.; Current World Environment, (2012), 7(1), 61-67, CAplus
Mass
- (1) Spectral data were obtained from John Wiley & Sons, Inc.
- (2) Attri, Pankaj; Journal of Physical Chemistry B, (2010), 114(42), 13415-13425, CAplus