四乙基四氟硼酸铵
Tetraethylammonium tetrafluoroborate
- 分子式：C8H20BF4N
- 分子量：217.06
- CAS编号：429-06-1
- 纯度：99%
基本信息
物性数据
| 项目 | 数据 | 测试条件 | 备注 | 数据来源 |
| 密度 g/mL | 1.22 | 20℃,101KPa | 晶体, gas displacement | ILThermo |
| 热分解温度 ℃ | 383 | |||
| 溶解性 | 全溶 | DMSO | 实验实测 | |
| 熔点 ℃ | 71 | DSC/DTA | ILThermo |
参考谱图
四乙基四氟硼酸铵,N2222BF4,429-06-1,Tetraethylammonium tetrafluoroborate,核磁 NMR, H谱, 氘代DMSO
安全信息
| Code |
Hazard Statement |
Source |
| H410 |
Very toxic to aquatic life with long lasting effects |
European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most common notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria |
| H401 |
Toxic to aquatic life |
Expert Curated |
| H372 |
Causes damage to organs through prolonged or repeated exposure |
Expert Curated, Japan GHS Classifications (Japanese) |
| H335 |
May cause respiratory irritation |
Acros Organics (Fisher Scientific), Acros Organics (part of Thermo Fisher Scientific), Alfa Aesar (a part of Thermo Fisher Scientific Chemicals, Inc.), European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most common notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, Japan GHS Classifications (Japanese), New Zealand Hazardous Substances and New Organisms (HSNO) Act - Classification of Chemicals, Sigma-Aldrich (Merck) |
| H332 |
Harmful if inhaled |
European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most common notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, Sigma-Aldrich (Merck) |
| H319 |
Causes serious eye irritation |
Acros Organics (Fisher Scientific), Acros Organics (part of Thermo Fisher Scientific), Alfa Aesar (a part of Thermo Fisher Scientific Chemicals, Inc.), European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most common notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, Japan GHS Classifications (Japanese), Sigma-Aldrich (Merck) |
| H318 |
Causes serious eye damage |
European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, New Zealand Hazardous Substances and New Organisms (HSNO) Act - Classification of Chemicals |
| H315 |
Causes skin irritation |
Acros Organics (Fisher Scientific), Acros Organics (part of Thermo Fisher Scientific), Alfa Aesar (a part of Thermo Fisher Scientific Chemicals, Inc.), European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most common notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, New Zealand Hazardous Substances and New Organisms (HSNO) Act - Classification of Chemicals, Sigma-Aldrich (Merck) |
| H314 |
Causes severe skin burns and eye damage |
European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated |
| H312 |
Harmful in contact with skin |
European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most common notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, Sigma-Aldrich (Merck) |
| H302+H312+H332 |
Harmful if swallowed, in contact with skin or if inhaled |
Expert Curated |
| H302 |
Harmful if swallowed |
Acros Organics (Fisher Scientific), Alfa Aesar (a part of Thermo Fisher Scientific Chemicals, Inc.), European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most common notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling - most serious notifications, European Chemical Agency (ECHA) Classification&Labelling Inventory - Notified classification and labelling according to CLP criteria, Expert Curated, Sigma-Aldrich (Merck) |
Other Names and Identifiers
Canonical SMILES
[F-][B+3]([F-])([F-])[F-].CC[N+](CC)(CC)CC
InChI
InChI=1S/C8H20N.BF4/c1-5-9(6-2,7-3)8-4;2-1(3,4)5/h5-8H2,1-4H3;/q+1;-1
InChI Key
XJRAKUDXACGCHA-UHFFFAOYSA-N
12 Other Names for this Substance
- Ammonium, tetraethyl-, tetrafluoroborate(1-) (8CI)
- Borate(1-), tetrafluoro-, N,N,N-triethylethanaminium (ZCI)
- Borate(1-), tetrafluoro-, tetraethylammonium (8CI)
- Ethanaminium, N,N,N-triethyl-, tetrafluoroborate(1-) (9CI)
- Tetraethylammonium tetrafluoroborate (7CI)
- Digirena
- LES 100
- Lipaste AN/EAF 1
- Lipaste P/EAFIN
- Merck Supercapacitor Electrolyte LES 100
- NSC 231537
- Tetraethylammonium tetrafluoroborate(1-)
参考文献
Experimental Properties
Chemical
Density
Electrical
Flow and Diffusion
Structure Related
Thermal
- (1) Herzig, Tobias; Journal of Chemical & Engineering Data, (2008), 53(2), 434-438, CAplus
- (2) Moe, N. S.; Acta Chemica Scandinavica, (1965), 19(4), 1023-4, CAplus
- (3) Wheeler, Charles M. Jr.; Journal of the American Chemical Society, (1955), 77, 2024-5, CAplus
- (4) Kobler, Heinz; Justus Liebigs Annalen der Chemie, (1978)(12), 1937, CAplus
- (5) Bhatt, Vasishta D.; Bulletin of Materials Science, (2013), 36(6), 1121-1125, CAplus
- (6) Lu, Zhenrong; Journal of Power Sources, (2006), 156(2), 555-559, CAplus
Experimental Spectra
1H-NMR
- (1) Sigma-Aldrich Co. LLC. (Spectral Data were obtained from John Wiley & Sons, Inc.)
- (2) Copyright Bio-Rad Laboratories. All Rights Reserved.
- (3) "Integrated Spectral Data Base System of Organic Compounds" data were obtained from the National Institute of Advanced Industrial Science and Technology (Japan)
- (4) Sigma-Aldrich (Spectral data were obtained from Advanced Chemistry Development, Inc.)
- (5) Koeppe, Benjamin; Journal of the American Chemical Society, (2011), 133(20), 7897-7908, CAplus
13C-NMR
- (1) Sigma-Aldrich Co. LLC. (Spectral Data were obtained from John Wiley & Sons, Inc.)
- (2) Copyright Bio-Rad Laboratories. All Rights Reserved.
- (3) "Integrated Spectral Data Base System of Organic Compounds" data were obtained from the National Institute of Advanced Industrial Science and Technology (Japan)
- (4) Sigma-Aldrich (Spectral data were obtained from Advanced Chemistry Development, Inc.)
- (5) Koeppe, Benjamin; Journal of the American Chemical Society, (2011), 133(20), 7897-7908, CAplus
IR
- (1) Sigma-Aldrich Co. LLC. (Spectral Data were obtained from John Wiley & Sons, Inc.)
- (2) Copyright Bio-Rad Laboratories. All Rights Reserved.
- (3) "Integrated Spectral Data Base System of Organic Compounds" data were obtained from the National Institute of Advanced Industrial Science and Technology (Japan)
Mass
(1) "Integrated Spectral Data Base System of Organic Compounds" data were obtained from the National Institute of Advanced Industrial Science and Technology (Japan)
Raman
- (1) Sigma-Aldrich Co. LLC. (Spectral Data were obtained from John Wiley & Sons, Inc.)
- (2) "Integrated Spectral Data Base System of Organic Compounds" data were obtained from the National Institute of Advanced Industrial Science and Technology (Japan)
- (3) Matsumoto, Kazuhiko; Chemistry Letters, (2012), 41(4), 394-396, CAplus
